Title: Professor, Inorganic and Theoretical Chemistry
Office: SZ 501
Phone: (252) 328-9759
Army High Performance Computing Research Center (1992-1994)
Postdoctoral Fellow, Minnesota Supercomputer Institute (1991-1992)
Ph.D., Texas A&M University (1991)
B.A., The Colorado College (1985)
"Utility of the Nudged Elastic Band Method in Identifying the Minimum Energy Path of an Elementary Organometallic Reaction Step," K. E. McPherson, L. J. Bartolotti, A. T. Morehead, A. L. Sargent, Organometallics. 2016, 35, 1861-1865
"Incorporation of fluorophore-cholesterol conjugates into liposomal and mycobacterial membranes," A. N. Wercholuk, J. M. Thuman, J. L. Stanley, A. L. Sargent, E. S. Anderson, W. E. Allen, Bioorg. Med. Chem. 2016, 24, 1045-1049.
"Anion binding by fluorescent Fmoc-protected amino acids," D. P. Farrell, A. L. Sargent, W. E. Allen, Supramol. Chem. 2016, 28, 45-52.
"Dimerization and Anion Binding of a Fluorescent Phospholipid Analogue," D. M. Jessen, A. N. Wercholuk, B. Xiong, A. L. Sargent, W. E. Allen, J. Org. Chem. 2012, 77, 6615-6619.
"Binding of Carboxylic Acids by Fluorescent Pyridyl Ureas," L.M. Jordan, P.D. Doyle, A.L. Sargent, W.E. Allen, J. Org. Chem. 2010, 75, 8450-8456.
"Wurster-Type' Ureas as Redox-Active Receptors for Anions," J. P. Clare, A. Statnikov, V. Lynch, A. L. Sargent, J. W. Sibert, J. Org. Chem. 2009, 74, 6637-6646.
"Fluorous Effects in Amide-Based Receptors for Anions," J. V. Gavette, J. M. McGrath, A. M. Spuches, A. L. Sargent, W. E. Allen, J. Org. Chem. 2009, 74, 3706-3710.
"Hydrogen Bonding vs Steric Gearing in a Hexasubstituted Benzene," J. V. Gavette, A. L. Sargent, W. E. Allen J. Org. Chem. 2008, 73, 3582-3584.
"Mechanism of Rhodium-Catalyzed Intramolecular Hydroacylation: A Computational Study," I. F. D. Hyatt, H. K. Anderson, A. T. Morehead Jr., A. L. Sargent, Organometallics 2008, 27, 135-147.
"On the Oxidation of Wurster's Reagent and the Wurster's Crown Analog of 15-Crown-5 in the Presence of Alkali Metal Cations," M. DeBacker, M. Hureau, M. Depriester, A. Deletoille, A. L. Sargent, P. B. Forshee, J. W. Sibert, J. Electroanal. Chem. 2008, 612, 97-104.
"Wurster's Crowns: A Comparative Study of ortho- and para-Phenylenediamine-Containing Macrocyclic Receptors," J. W. Sibert, P. B. Forshee, G. R. Hundt, A. L. Sargent, S. G. Bott, V. Lynch, Inorg. Chem. 2007, 46, 10913-10925.
"An Interactive Computer Program to Help Students Learn Molecular Symmetry Elements and Operations," D. E. Meyer, A. L. Sargent, J. Chem. Educ. 2007, 84, 1551-1552.
"A Theoretical Investigation on the Wurster's Crown Analogue of 18-Crown-6," A. L. Sargent, B. J. Mosley, J. W. Sibert, J. Phys. Chem. A 2006, 110/10, 3826-3837.
"Wurster's Crownophanes: An Alternate Topology for para-Phenylenediamine-Based Macrocycles," J. W. Sibert, G. R. Hundt, A. L. Sargent, V. Lynch, Tetrahedron 2005, 61/52, 12350-12357.
"Participation of Host 'Spacer' Atoms in Carboxylic Acid Binding: Implications for Amino Acid Recognition," D. K. Barnhill, A. L. Sargent, W. E. Allen, Tetrahedron 2005, 61/35, 8366-8371.
"Dynamic Disorder and Conformer Exchange in the Crystalline Monomer of Polycarbonate," J. E. Wolak, J. Knutson, J. D. Martin, P. Boyle, A. L. Sargent, J. L. White, J. Phys Chem. B 2003, 107, 13293-13299.
"Global vs. Local Aromaticity in Porphyrinoid Macrocycles: Experimental and Theoretical Study of 'Imidacene,' an Imidazole-Containing Analogue of Porphycene," A. L. Sargent, I. C. Hawkins, W. E. Allen, H. Liu, J. L. Sessler, C. J. Fowler, Chem. Eur. J. 2003, 9, 3065-3072.
"C-S and C-H Bond Activation of Thiophene by Cp*Rh(PMe3): A DFT Theoretical Investigation," A. L. Sargent and E. P. Titus, Organometallics, 1998, 17, 65-77.
"Electronic Structure of Axially Ligated Rhodium Carboxylates: pi Back-Bonding Revisited," A. L. Sargent, M. E. Rollog and C. T. Eagle, Theor. Chem. Acc., 1997, 97, 283-288.
"Poly(Thienyl)Borates: An Investigation Into the Coordination of Thiophene and Its Derivatives," A. L. Sargent, E. P. Titus, C. G. Riordan, A. L. Rheingold and P. Ge, Inorg. Chem., 1996, 35, 7095-7101.
"Enzyme-Catalyzed Enolization Reactions: A Theoretical Study on the Energetics of Concerted and Stepwise Pathways," A. L. Sargent, M. E. Rollog, J. Almlof, P. G. Gassman and J. Gerlt, J. Molec. Struct. (THEOCHEM), 1996, 388, 145-159.
"Massively Parallel Algorithms for Electronic Structure Calculations in Quantum Chemistry," A. L. Sargent, J. Almlof and M. W. Feyereisen, in Applications on Advanced Architecture Computers, G. Astfalk, Ed., Vol. 1, 1996, 1-13.
"Electron Delocalization in Helical Bis(quinone) Anion Radicals," A. L. Sargent, J. Almlof, and C. A. Liberko, J. Phys. Chem., 1994, 98, 6114-6117.
"Massively Parallel Algorithms for Electronic Structure Calculations in Quantum Chemistry," A. L. Sargent, J. Almlof, and M. W. Feyereisen, SIAM News, 1993, 26(1), 14.
"Theoretical Studies of Inorganic and Organometallic Reaction Mechanisms. 4. The Oxidative Addition of Dihydrogen to d8 Square-Planar Iridium Complexes With Trans Phosphines," A. L. Sargent and M. B. Hall, Inorg. Chem., 1992, 31, 317-321.
"Theoretical Studies of Inorganic and Organometallic Reaction Mechanisms. 3. The Origin of the Difference in the Barrier for the Kinetic and Thermodynamic Products for the Oxidative Addition of Dihydrogen to a Square-Planar Iridium Complex," A. L. Sargent, M. B. Hall, and M. F. Guest, J. Am. Chem. Soc., 1992, 114, 517-522.
"The Oxidative Addition of H2 to d8 Square-Planar Iridium Complexes," A. L. Sargent and M. B. Hall, in Topics in Physical Organometallic Chemistry, Vol. 4, M. Gielen, Ed., Freund Pub.: London, England, 1992; pp 1-39.
"Basis Sets for Geometry Optimizations of Second-Row Transition Metal Inorganic and Organometallic Complexes," Sargent, A. L.; Hall, M. B. J. Comp. Chem. 1991, 12, 923‑933.
"Linear Semibriding Carbonyls - 3. Carbonyl and Thiocarbonyl Ligands as Four‑Electron Donors," Sargent, A. L.; Hall, M. B. Polyhedron, 1990, 15/16, 1799‑1808.
"Linear Semibridging Carbonyls - 2. Heterobimetallic Complexes Containing a Coordinatively Unsaturated Late Transition Metal Center," Sargent, A. L.; Hall, M. B. J. Am. Chem. Soc. 1989, 111, 1563‑1569.